Scientists use the sun to convert CO2 into high-energy fuel

February 28th, 2009 - 2:40 pm ICT by ANI  

Washington, Feb 28 (ANI): A team of scientists at Penn State University has come up with an ingenious method of turning captured CO2 into methane, a combustible fuel, using the energy of the sun.

The team, led by Craig Grimes, described a highly efficient photocatalyst that can yield significant amounts of methane, other hydrocarbons, and hydrogen in a simple, inexpensive process.

The team used arrays of nitrogen-doped titania nanotubes sputter-coated with an ultrathin layer of a platinum and/or copper co-catalyst(s).

The titania captures high energy ultraviolet wavelengths, while the copper shifts the bandgap into the visible wavelengths to better utilize the part of the solar spectrum where most of the energy lies.

In addition, the thin-walled nanotubes increase the transport ability of the charge carriers by reducing the chance for recombination of the electron with the hole.

The nanotube arrays were placed inside a stainless steel chamber filled with carbon dioxide infused with water vapor.

The chamber was then set outdoors in sunlight. After a few hours, the team measured the amount of CO2 converted into useful fuels.

The results showed 160 uL of methane per hour per gram of nanotubes, a conversion rate approximately 20 times higher than previous efforts done under laboratory conditions using pure UV light.

Copper oxide and titanium dioxide are common materials, Grimes said. We can tune the reaction using platinum nanoparticles or ideally other, less expensive catalysts, he added.

According to Grimes, the conversion process can readily be improved by several orders of magnitude, which could make the process economically feasible.

You could have a small scale solar condenser and a concentrated source of CO2 in a closed loop cycle to make a portable fuel. Its a good way of storing energy for when the sun goes down, he suggested.

Inexpensive solar concentrators could improve the process, as the photocatalytic CO2 conversion appears to scale with the intensity of sunlight.

Capturing CO2 at source points, such as fossil fuel (coal, natural gas, etc.), burning power plants, and turning it into a transportation fuel in a cheap, sunlight-driven process could dramatically improve the economics of CO2 capture.

Then maybe we could figure out how to capture and reuse the CO2 in our vehicles and none of it would go back into the atmosphere, Grimes proposed. (ANI)

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