Polymer synthesis to pave way for more energy-efficient electronicsJuly 20th, 2010 - 4:46 pm ICT by ANI
Washington, July 20 (ANI): Television and computer screens are set to get brighter, clearer and more energy-efficient, thanks to a process developed by a team of American and Canadian scientists.
The synthesis of a conjugated organic polymer - widely used as a conductive material in devices like light-emitting diodes, televisions and solar cells - could mean more efficient, cheaper electronics.
In a paper published in the Proceedings of the National Academy of Sciences, the group of researchers from US Department of Energy’s Oak Ridge National Laboratory (ORNL) and two Canadian universities outlined their success in growing highly structured short chains of polymer poly(3,4-ethylenedioxythiophene), or PEDOT. Analysis and understanding of the polymerization process and results were provided with the help of ORNL supercomputers.
The theoretical expertise provided by ORNL scientists Bobby Sumpter and Vincent Meunier in synthesizing the PEDOT polymer could potentially have an impact on everyday electronic products. PEDOT is valued in electronic applications for the transparency, ductility and stability of its conducting, or doped, state. Because of its role as conductive material in organic light-emitting diodes, PEDOT is found in many electronic devices such as televisions and computer monitors.
The polymer is also used in many solar panel cells as a hole-filling material. “It’s one of the most successfully used semiconducting polymers on the planet,” Sumpter said.
Improving and controlling the molecular order of a nanostructured PEDOT material is critical to the polymer’s performance in electronic applications. The highly ordered polymer arrays such as those constructed by the researchers could lead to increased efficiencies in a multitude of electronic devices.
To create ordered arrays of the PEDOT polymer, the team placed a precursor molecule onto a copper crystalline surface, which helped to guide and initiate the polymerization reaction. Team member Meunier of ORNL compared the process to placing eggs in an egg carton, where the free energy minima, or “indentations,” in the copper surface allow the molecules to neatly stack next to each other to form a compact and organized polymer structure.
“The chemistry and resulting stereochemical structure on the surface are very unusual. Most attempts to synthesize polymers usually result in imperfect polymer arrays with a very different prominent structure,” said Sumpter.
Sumpter and Meunier from ORNL’s Center for Nanophase Materials Sciences with appointments in the Computer Science and Mathematics Division collaborated in the project by analysing the results through a “virtual microscope.” Based on density functional theory calculations and simulations performed on ORNL supercomputers, the “virtual microscopy” revealed the highly organized structure of the polymer arrays.
By examining the polymer formation with the conventional means of scanning tunnelling microscopy combined with the virtual microscopy, the team was able to clearly illustrate the construction and bonding of PEDOT arrays.
Meunier said: “This experiment defines what nanoscience is about–a mixture of experimental techniques combined with theoretical knowledge. It was an excellent opportunity to interface directly with experimentalists and establish new international collaborations.” (ANI)
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