Gold surprisingly gets harder, not softer, when scientists heat it up

January 23rd, 2009 - 5:23 pm ICT by ANI  

Washington, January 23 (ANI): While heating is generally known to cause any article to become softer, University of Toronto researchers have shown exactly the opposite effect on gold.
It is counter-intuitive but the gold got harder instead of softer,” says Chemistry and Physics professor R.J. Dwayne Miller.
Can you imagine a blacksmith heating up gold to pound it thinner, only to find it got harder? But we heated the gold at terrific heating rates greater than 1 billion million degrees per second that approach the temperature of the interior of stars, the researcher added.
Describing their study in the journal Science, the researchers revealed that the gold was heated at rates too fast for the electrons absorbing the light energy to collide with surrounding atoms and lose energy.
This means the electrons are on average further away from the atomic nucleus and there is less screening of the positive nuclear charge by these heated electrons. The bonds between atoms actually got stronger, he said.
A gold crystal consists of gold ions and weakly bound electrons which screen the repulsive forces between the ions, explained lead author Ralph Ernstorfer, a former postdoctoral research fellow with Prof. Miller, who is now at the Max-Planck Institute for Quantum Optics in Garching and the TU Munich, Germany.
In contrast to many other materials, heating the electrons in gold with an ultra-short laser pulse makes the forces between the ions stronger, resulting in a harder lattice with an increased melting point.
The effect of bond hardening in gold has been theoretically predicted. Now we have actually observed it for the first time, says Ernstorfer.
The researchers employed a technique called femtosecond electron diffraction to make the observation, and record the atomic motions of the ions in real time while heating the material with lasers.
By measuring the speed of heating, amplitude of the atomic motions, and ultimate melting of the crystal, the laser-induced change of the lattice stability could be inferred.
We now have an atomic-level view of this rarified state of matter, referred to as warm dense matter, and can relate the observed liquid structure to the increased lattice stability, says Miller. (ANI)

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